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codeine pills effects This formula also imposes a direction on to time; whereas every other physical law we know of would work the same whether time was going forwards or backwards, this is not true for the second law of thermodynamics. However long you leave it, a boiling pan of water is unlikely to ever become a block of ice. A smashed plate could never reassemble itself, as this would reduce the entropy of the system in defiance of the second law of thermodynamics. Some processes, Carnot observed, are irreversible.